Pd-on-Si catalysts prepared via galvanic displacement for the selective hydrogenation of para-chloronitrobenzene.

نویسندگان

  • Qian Wei
  • Yu-Sheng Shi
  • Ke-Qiang Sun
  • Bo-Qing Xu
چکیده

The direct redox reaction (galvanic displacement) between Pd(2+) and substrate Si was used to deposit Pd on Si, and the Pd-Si catalysts enabled a chemoselective hydrogenation of para-chloronitrobenzene with the selectivity for para-chloroaniline higher than 99.9% at complete conversion of para-chloronitrobenzene.

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عنوان ژورنال:
  • Chemical communications

دوره 52 14  شماره 

صفحات  -

تاریخ انتشار 2016